Her Way: Ali Larter

The ever-fresh-faced Ali Larter started modeling when she was 13, so she's had ample opportunity to hone her personal style. "I understand what looks good on me now," the 34-year-old actress explains. "I used to overcomplicate it and be a bit more trendy and funky, but at the end of the day, I always feel sexiest in a pair of blue jeans and a white shirt." Not that getting this look right doesn't come without its finer points: Sometimes the simplest, most pared-down outfit is also the most difficult to nail. But Larter is fixated on the all-important details of fit. "I tailor everything," she says. "The littlest nip can change a shirt." Amazingly, however, when Larter slipped on the Myne blouse at left, she found that it was very nearly perfect. "The button placement here is spot-on," she noted, eyeing it covetously. "A few of my white button-downs have just kicked it, so it's time for new ones!"